Yes, you will want to use some silicone sealant. Use it on the gasket, on both sides around the water passages, in the corners and where gaskets join. I also apply a thin coat around the outer surface of the crankshaft seal, (The metal part), before installing. Don't forget to apply a coat of oil or grease to the lips on the seal for lubrication where it rides against the balancer. Friction will ruin the seal if there isn't any lube there.
I use a spray on gasket sealer called "Copper Coat" on both sides of the paper and cork gaskets. When dry, it leaves a tacky surface and it helps to keep the gaskets in position. Most part stores have it.
The curved seal that sits on the bottom of the cover should have some silicone applied to the portion that sits inside of the groove on the cover and on the ends where it meets the other gaskets. Use just enough silicone for a good seal, don't over do it. Use your judgment. If the curved gasket makes good contact with the oil pan, you can either leave it alone or apply a light coat of the silicone to that surface, but you will definitely need some in the corners. Use the service manual as a guide.
I apply the silicone straight from the tube, but it helps to use something like a popsicle stick or a finger to spread it out. If the stick is too wide, cut it down to size. I don't recommend cutting down your finger, though.
