Not sure about the ECT sensor... however if hot coolant is getting back to your overflow (hich is connected to the radiator), then hot coolant is getting back to your radiator (via an open thermostat).
Usually the reason overflows overflow is because of a bad radiator cap. I would invest in that $3 part before looking for other issues.
Usually the reason overflows overflow is because of a bad radiator cap. I would invest in that $3 part before looking for other issues.