You should always stick to the pressure listed by Ford for the applicable tires size, so if you have changed tire size on your car then you will have to figure it out.
Now, some Mustangs came with the 245/45/19 tires(GT/SC and regular GT's with optional 19 premium wheels) so find out what Ford recommends for those cars and use that.
Also, the 215/65-17's on V6 automatic cars are setup for 35 psi because those are the gas saver tires.
NEVER run the tires at the max psi setting listed on the sidewall. Running the tire pressure that high, or even appreciably higher than the standard setting will cause the mentioned rough ride and will also cause the center ribs of the tread to wear faster than the outer edges.
Running a slightly higher air pressure can help with fuel economy but like I said, it can also make the tires wear incorrectly.