This is fragmentary advice.. I may not have it all correct so I welcome anyone correcting me ....
You have to find cylinder#1, and know the firing order of a small-block Ford. I think#1 is closest to the radiator on the passenger side of the hood.
Disconnect the battery so that you don't start the engine by turning her over and get your arm mangled in the fan/belts should she want to start ( you say she is so out of time that this may not happen, but you don't want to lose any limbs here ... )
Take out the spark plug to #1. Suggest you use a socket wrench to turn the crank pully, do so until you hear the rush of air indicating the piston has travelled all the way up the stroke ( this is called Top Dead Center, or TDC ). Since the head is installed and you only have the spark plug hole, you can't see this very well/at all, unless you have a the neck of a giraffe.
If you stick your finger in the hole you should feel the rush of air as she comes up towards the cylinder head ( compression ).
Now you get the distributor assembly, find which wire is to #1. Make sure the rotor is right underneath the terminal to cylinder / wire #1.
This may take some doing to attempt to keep the distributor shaft from turning...Set the distributor in and secure with the bolt. It ought to be facing front like all normal appearances ( not towards the firewall ! )
Reinstall the spark plug to #1, and reconnect the spark plug wire and the battery. Hit the starter and pray ( a lot ). If she runs, get a timing light on her and set to specs.
The aim of all of this is to get the piston where it should be mechanically ( top of the stroke ) with the rotor positioned under #1 spark plug wire so when the current shoots thru to generate a spark from the plug the piston is where it should be at Top Dead Center.
When I was in my later teen years, I took the heads off the 289 that was in our Country Squire wagon and had a valve job done on the heads, then reassembled the heads/intake etc. I think I marked the distributor before I pulled her out ( chalk/paint marks on the engine & side of the distributor but I remember it was touchy setting her back in. I did this in the early/mid 1970's so it is long ago. A '67 289 was very simple to work on but yours is still a small block Ford ( still my favorite engine of all time ).
Good Luck, and see if you get any other advice from other forum members before you proceed. I'm going on memeories of almost 40 years ago....:kooky: