The 6s used different distributors for TE cars, the V8s did not. The V8 TE just had different advance curves in the same unit which is how you can use the same Pertronix for 25 years.
Ted I believe you have a 289, 2V, TE, car. The attached graph shows the advance curves for EVERY V8 Mustang, Comet, Fairlane and Falcon produced in 1966 taken from the Ford shop manual. There are NONE of them that ever had more than 28 degrees centrifugal advance at 3500 RPM and the ones with the most advance are TE cars! What I plotted is the average of the advance range given at each RPM. If you take the range into account then your 23 degrees is probably at the bottom end or the range but still within spec. If you switch to a non-TE distributor you will get less advance not more. This plot easily makes a lie out of the common assumption that a TE distributor had an awful advance curve. They could be more aggressive than the others probably to make up for the retarded static timing.
Remember that the plot is in distributor RPM and distributor degrees so 3500 RPM for the engine is 1750 on the chart and that 14 degrees on the chart is 28 crankshaft degrees advance. The lines are a little hard to decipher but the two very top ones, the blue and yellow ones are for manual and automatic, 2V, TE, 289s. Their max advance stop is set at 16 degrees (32 deg crank) and they wouldn't reach that until about 4500 engine RPMs. The engines with the least amount of advance, again (light) blue and yellow lines on the bottom right corner, are the A-code and even the HiPo engines. The HiPO had no vacuum advance so that light blue curve on the very bottom is all the advance they ever got and at 3500 engine RPM that was only around 17 degrees advance. Even though the non-TE, 4V distributors had a stop set at 14 degrees the engines would have had to turn about 10K RPM (not gonna happen) to ever reach that 28 degrees of advance.
For the 4V 289s the yellow line just above the HiPo is for both manual and automatic. That non-TE line is well below the pair of 4V TE lines that are the purple/pink pair that at 1000 distributor RPM are just below the top two 2V TE lines. So any TE 289 had a more agressive centrifugal advance curve than the corresponding non-TE version.
The 'curves' that look almost like straight lines more to the bottom for most of the RPM range are the 390 cars.